Compositional disorder in frans-[RhBr0.26Cl0.74H(PMe3) 4]-[B(1,2-O2C6Br4)]·CH 2Cl2

Nicholas C. Norman, A. Guy Orpen, Michael J. Quayle, Edward G. Robins

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

The structure of trans-(bromo/chloro)hydridotetrakis(trimethylphosphine)rhodium(III) bis(tetrabromopyrocatecholato-O,O′)borate dichloromethane solvate, [RhCl0.74Br0.26H-(C3H9P) 4](C12BBr8O4)·CH 2Cl2, is reported. The RhIII complex shows bromine/chlorine compositional disorder with a trans arrangement of the hydride and halide ligands. The anion has approximate D2d symmetry, with a central spiro-B atom distorted from regular tetrahedral geometry by the small chelating O-B-O angles.

Original languageEnglish
Pages (from-to)50-52
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume56
Issue number1
DOIs
Publication statusPublished or Issued - Jan 2000
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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