Abstract
The structure of trans-(bromo/chloro)hydridotetrakis(trimethylphosphine)rhodium(III) bis(tetrabromopyrocatecholato-O,O′)borate dichloromethane solvate, [RhCl0.74Br0.26H-(C3H9P) 4](C12BBr8O4)·CH 2Cl2, is reported. The RhIII complex shows bromine/chlorine compositional disorder with a trans arrangement of the hydride and halide ligands. The anion has approximate D2d symmetry, with a central spiro-B atom distorted from regular tetrahedral geometry by the small chelating O-B-O angles.
Original language | English |
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Pages (from-to) | 50-52 |
Number of pages | 3 |
Journal | Acta Crystallographica Section C: Crystal Structure Communications |
Volume | 56 |
Issue number | 1 |
DOIs | |
Publication status | Published or Issued - Jan 2000 |
Externally published | Yes |
ASJC Scopus subject areas
- General Biochemistry,Genetics and Molecular Biology