Abstract
The PdCl2(Cy∗Phine)2 precatalyst containing the meta-terarylphosphine ligand, Cy∗Phine, can effectively mediate decarboxylative cross-coupling with a diverse range of (hetero-)aryl, aryl and alkyl chlorides including those with unprotected functionality. Using a facile and robust protocol, this process was extended to the first synthesis of symmetrical di(heteroaryl)alkynes via tandem Sonogashira/decarboxylative cross-coupling of heteroaryl chlorides and propiolic acid.
Original language | English |
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Pages (from-to) | 72810-72814 |
Number of pages | 5 |
Journal | RSC Advances |
Volume | 6 |
Issue number | 76 |
DOIs | |
Publication status | Published or Issued - 2016 |
Externally published | Yes |
ASJC Scopus subject areas
- General Chemistry
- General Chemical Engineering