Synthesis and reactivity of [18F]-N-fluorobenzenesulfonimide

Harriet Teare, Edward G. Robins, Erik Årstad, Sajinder K. Luthra, Véronique Gouverneur

Research output: Contribution to journalArticlepeer-review

92 Citations (Scopus)

Abstract

A novel [18F]NF reagent and two novel radiochemical transformations have been developed: [18F]NFSi has been prepared from sodium dibenzenesulfonimide and reacted in the presence of silyl enol ethers and allylsilanes to deliver labelled fluorinated ketones and allylic fluorides respectively; the radiosynthesis of the fluorinated A ring of vitamin D 3 has also been completed with success.

Original languageEnglish
Pages (from-to)2330-2332
Number of pages3
JournalChemical Communications
Issue number23
DOIs
Publication statusPublished or Issued - 2007
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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